William Crockford | All the action from the casino floor: news, views and more

William Crockford | All the action from the casino floor: news, views and more

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The fossil red alga Bangiomorpha pubescens is the only recognized crown-group eukaryote older than ca.

Because it postdates the divergence between the red and green algae and the prior endosymbiotic event that gave rise to the chloroplast, B.

However, molecular clock estimates for the divergence between the red and green algae are highly variable, and some analyses estimate this split to be younger than the widely inferred but poorly constrained first appearance age of 1.

As a result, many molecular clock studies reject this fossil ex post facto. Here we present new Re-Os isotopic ages from sedimentary rocks that stratigraphically bracket the occurrence of B.

This date is m. Using cross-calibrated molecular clock analyses with the new fossil age, we calculate that photosynthesis within the Eukarya emerged ca.

This date for primary plastid endosymbiosis serves as a benchmark for interpreting the fossil record of early eukaryotes and evaluating their role in the Proterozoic biosphere.

Linking paleocontinents through triple oxygen isotope anomalies. A central tenet of the Neoproterozoic snowball Earth hypothesis is that glaciations ended synchronously.

Although this condition is borne out by U-Pb and Re-Os geochronology, the time scale of deglaciation is much less than the intrinsic error of the highest resolution dating techniques, and consequently calibrating the pace and synchronicity of biogeochemical recovery from Cryogenian glaciations remains a challenge.

Given the importance of obtaining a globally synoptic view of paleoenvironmental conditions and biological evolution during these extraordinary transitions, robust correlations and chronologies are imperative.

The global footprint of this geochemical signal coupled to its short duration provides a unique time datum that can be used to cross-correlate Marinoan postglacial cap carbonate sequences and track the geochemical evolution of the oceans during deglaciation.

Geochemical analyses of sedimentary barites barium sulfates in the geological record have yielded fundamental insights into the chemistry of the Archean environment and evolutionary origin of microbial metabolisms.

However, the question of how barites were able to precipitate from a contemporary ocean that contained only trace amounts of sulfate remains controversial.

Here we report dissolved and particulate multi-element and barium-isotopic data from Lake Superior that evidence pelagic barite precipitation at micromolar ambient sulfate.

These pelagic barites likely precipitate within particle-associated microenvironments supplied with additional barium and sulfate ions derived from heterotrophic remineralization of organic matter.

If active during the Archean, pelagic precipitation and subsequent sedimentation may account for the genesis of enigmatic barite deposits.

Indeed, barium-isotopic analyses of barites from the Paleoarchean Dresser Formation are consistent with a pelagic mechanism of precipitation, which altogether offers a new paradigm for interpreting the temporal occurrence of barites in the geological record.

Chuos Sturtian or Ghaub Marinoan Formation? Tectonostratigraphy and radiogenic chemostratigraphy of the ca. Bridging the gap between the foreland and hinterland II: Geochronology and tectonic setting of Ordovician magmatism and basin formation on the Laurentian margin of New England and Newfoundland.

Ordovician strata of the Mohawk Valley and Taconic allochthon of New York and the Humber margin of Newfoundland record multiple magmatic and basin-forming episodes associated with the Taconic orogeny.

Here we present new U-Pb zircon geochronology and whole rock geochemistry and neodymium isotopes from Early Paleozoic volcanic ashes and siliciclastic units on the northern Appalachian margin of Laurentia.

Red, bioturbated slate of the Indian River Formation record a shift to more juvenile neodymium isotope values suggesting sedimentary contributions from the Taconic arc-system by Ma.

Eight ashes within the Trenton Group in the Mohawk Valley were dated between These ashes contain zircon with Late Ordovician magmatic rims and 1.

The new geochronological and geochemical data are integrated with a subsidence model and data from the hinterland to refine the tectonic model of the Taconic orogeny.

Closure of the Iapetus Ocean by Ma via collision of the peri-Gondwanan Moretown terrane with hyperextended distal fragments of the Laurentian margin is not clearly manifested on the autochthon or the Taconic allochthon other than an increase in sediment accumulation.

Pro-foreland basins formed during the Middle Ordovician when these terranes were obducted onto the Laurentian margin. Following slab reversal, by Ma, the Bronson Hill arc was established on the new composite Laurentian margin.

Thus, we conclude that Late Ordovician strata in the Mohawk Valley and Taconic allochthon of New York and on the Humber margin of Newfoundland were deposited in retro-foreland basins.

Bacterial sulfur disproportionation constrains timing of Neoproterozoic oxygenation. Various geochemical records suggest that atmospheric O-2 increased in the Ediacaran Ma , broadly coincident with the emergence and diversification of large animals and increasing marine ecosystem complexity.

Furthermore, geochemical proxies indicate that seawater sulfate levels rose at this time too, which has been hypothesized to reflect increased sulfide oxidation in marine sediments caused by sediment mixing of the newly evolved macrofauna.

However, the exact timing of oxygenation is not yet understood, and there are claims for significant oxygenation prior to the Ediacaran.

Furthermore, recent evidence suggests that physical mixing of sediments did not become important until the late Silurian.

Here we report a multiple sulfur isotope record from a ca. We present isotopic evidence for onset of globally significant bacterial sulfur disproportionation and reoxidative sulfur cycling following the Ma Marinoan glaciation.

Widespread sulfide oxidation helps to explain the observed first-order increase in seawater sulfate concentration from the earliest Ediacaran to the Precambrian-Cambrian boundary by reducing the amount of sulfur buried as pyrite.

Expansion of reoxidative sulfur cycling to a global scale also indicates increasing environmental O-2 levels.

Thus, our data suggest that increasing atmospheric O-2 levels may have played a role in the emergence of the Ediacaran macrofauna and increasing marine ecosystem complexity.

Basin redox and primary productivity within the Mesoproterozoic Roper Seaway. It is interpreted to have been deposited in a large epeiric sea known as the Roper Seaway.

Trace element data suggest that the redox structure of the basin was a shallow oxic layer overlying deeper suboxic to anoxic waters along with a prominent episode of euxinia.

These anoxic and sulfidic conditions, as inferred by Mo, V, and U concentrations molybdenum, vanadium and uranium , developed due to high organic carbon loading consistent with models that suggest that euxinic conditions cannot develop until the flux of organic matter is significantly greater than the flux of bioavailable iron, which permits sulphate reduction to proceed.

This is further supported by prominent negative cerium anomalies within these shales, indicative of active oxidative redox cycling of cerium. We propose that the high organic matter flux was the result of increased nutrient loading to the Roper Seaway from weathering of the continental hinterland.

This switch in provenance would have increased phosphorus delivery to the Roper Seaway, contributing to high primary productivity and the onset of euxinia.

This dataset and model serve as a basis for understanding the temporal evolution of the deepest sections of the Roper Seaway and finer scale changes in the environment at this time.

Organic and inorganic geochemistry of the Mesoproterozoic Roper Seaway. Jun Australian Earth Sciences Convention. Indigenous extractable biomarkers from the Roper Seaway describe a water column dominated by cyanobacteria with large scale heterotrophic bacterial reworking of the organic matter either occurring within the water column, or in microbial mats.

Evidence for microbial reworking includes a large unresolved complex mixture UCM and high ratios of monomethyl alkanes relative to n-alkanes— characteristic features of indigenous Proterozoic bitumen.

The 2,3,4- and 2,3,6- trimethyl monoaryl isoprenoid series, commonly used biomarkers for photic zone euxinia, were below detection limits in all samples analysed, suggesting that the photic zone of the Roper Seaway was not euxinic.

Complementary trace element data also supports this observation with a negative cerium anomaly hosted in the black shales. Steranes, biomarkers for single-cell and multicellular eukaryotes, were below detection limits in all extracts analysed, although probable eukaryotic microfossils have been identified in the same drillcore analysed in this study.

These results suggest that eukaryotes, while present in the Roper Seaway, were ecologically restricted and contributed little to the net biomass.

Trace element data suggest that the shallow oxic layer overlay deeper anoxic to intermittently euxinic waters in the Roper Seaway.

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The tone of the club was excellent. A most gentleman-like feeling prevailed, and none of the rudeness, familiarity, and ill-breeding which disgrace some of the minor clubs of the present day, would have been tolerated for a moment.

This in turn meant that Crockford had to attract gentlemen and aristocrats, rather than, say, self-made businessmen. Click to view in higher resolution.

The noble Lord, however, had undeniable prospective resources. It was an epitaph that, one suspects, the former fishmonger would have considered quite a compliment.

Life in Regency and Early Victorian Times: Mike — love your articles. Great stuff — you always give an interesting angle on both familiar and obscure topics of history.

I enjoyed the article on Crockford: I am a descendant: My mother was nicknamed Crocky. Just looking into family history myself and seems this is also a possibility for my family line of Crockfords.

Would be great to see a tree other than what ancestry. Fascinating article, details of which are well recorded at least within the family.

I think my g-g-g grandfather had an ability to stay calm under pressure and to ensure the bank always rose to whatever challenge was placed before it.

He was just about a child of his time. You are commenting using your WordPress. You are commenting using your Twitter account.

We propose that the high organic matter flux was the result of increased nutrient loading to the Roper Seaway from weathering of the continental hinterland.

This switch in provenance would have increased phosphorus delivery to the Roper Seaway, contributing to high primary productivity and the onset of euxinia.

This dataset and model serve as a basis for understanding the temporal evolution of the deepest sections of the Roper Seaway and finer scale changes in the environment at this time.

Organic and inorganic geochemistry of the Mesoproterozoic Roper Seaway. Jun Australian Earth Sciences Convention. Indigenous extractable biomarkers from the Roper Seaway describe a water column dominated by cyanobacteria with large scale heterotrophic bacterial reworking of the organic matter either occurring within the water column, or in microbial mats.

Evidence for microbial reworking includes a large unresolved complex mixture UCM and high ratios of monomethyl alkanes relative to n-alkanes— characteristic features of indigenous Proterozoic bitumen.

The 2,3,4- and 2,3,6- trimethyl monoaryl isoprenoid series, commonly used biomarkers for photic zone euxinia, were below detection limits in all samples analysed, suggesting that the photic zone of the Roper Seaway was not euxinic.

Complementary trace element data also supports this observation with a negative cerium anomaly hosted in the black shales.

Steranes, biomarkers for single-cell and multicellular eukaryotes, were below detection limits in all extracts analysed, although probable eukaryotic microfossils have been identified in the same drillcore analysed in this study.

These results suggest that eukaryotes, while present in the Roper Seaway, were ecologically restricted and contributed little to the net biomass.

Trace element data suggest that the shallow oxic layer overlay deeper anoxic to intermittently euxinic waters in the Roper Seaway.

The deep water anoxic and sulfidic conditions are inferred by the trace element abundances of molybdenum, vanadium and uranium which developed due to high organic carbon loading.

This switch in provenance would have provided an increase in phosphorus delivery to the Roper Seaway, contributing to high primary productivity and the onset of euxinia, hence promoting organic matter preservation.

The complementary inorganic and organic datasets and model serve as a basis for understanding the temporal evolution of the deepest sections of the Roper Seaway, finer scale changes in the palaeo-environment and microbial diversity at this time and highlights the strength of a multidisciplinary approach.

Triple oxygen and multiple sulfur isotope constraints on the evolution of the post-Marinoan sulfur cycle. Searching for an extinction event at the end of the Earth.

Disentangling the events surrounding the K-Pg extinction remains hotly debated with specific questions unanswered about the kill mechanism of both terrestrial and aquatic species, and the response of the marine environment to these events.

Evidence has been presented that shows surface water foraminifera being severely impacted, however it is still unclear if global primary production was significantly affected.

Novel isotopic techniques emerging are providing new insights to the geologic record, specifically Zn isotopes are showing promise as a proxy for paleo-productivity.

Here we present new data from IODP core A, currently located approximately km east of Japan, spanning events before, during and after the K-Pg transition.

Preliminary eNd, results show a primitive signal, with an average value of Exploring possible impacts on global productivity, d66Zn values indicate that despite the dramatic events unfolding, seawater isotope ratios recorded in carbonates deposited on the other side of the Earth saw no significant changes in these isotope ratios.

Mercury in some arc crustal rocks and mantle peridotites and relevance to the moderately volatile element budget of the Earth. Characterizing the sedimentary provenance of Pre-Mississippian stratigraphy on the North Slope sub-terrane of Arctic Alaska.

The Arctic Alaska terrane is critical for reconstructing the Paleozoic and Mesozoic tectonic evolution of the Arctic.

The oldest rocks exposed on the North Slope subterrane consist of a late Neoproterozoic to early Paleozoic carbonate platform surrounded by poorly understood basinal siliciclastic and mafic volcanic rocks.

A significant portion of these siliciclastic strata are grouped into the broadly defined Neruokpuk Formation and Road River Group, which have been correlated with units exposed in northwestern Laurentia.

Here, we present sedimentary provenance data, including Nd isotope geochemistry, bulk major and trace element geochemistry, and thin section point counting on samples of shale, phyllite, and sandstone collected from these map units with the goal of providing detailed characterization and regional correlation of the pre-Mississippian stratigraphy of the North Slope.

When combined with paleontological and geochronological age constraints on these strata, these data demonstrate multiple distinct and identifiable provenance signatures, indicating discrete shifts in sediment sources during latest Neoproterozoic—Devonian basin evolution.

Although precise age constraints are lacking, the broad timing of the shift in the provenance of siliciclastic strata on the North Slope subterrane of Arctic Alaska is consistent with tectonic and paleogeographic links to the Caledonian and Ellesmerian orogenies of northeastern Laurentia.

The importance of complex brine chemistry on reaction rates. Synthetic brine yielded faster rates of reaction than natural brines.

Experi-ments performed on synthetic brines, spiked with 10 mmol of either Sr or Zn, suggest that enhanced reac-tion rates observed in synthetic brines are due to a lack of trace ion interaction with mineral surfaces.

Dissolution rates extrapolated from experiments predict that CO 2 injected into the Keg River Formation will dissolve a very minor portion of rock in contact with affected formation waters.

This work is part of a site characterization study, which aims to assess the viability of such a project in the province. Dissolution rates of Keg River carbonates immersed in Keg River brines collected in May were measured.

Results are higher but within an order of magnitude of literature values at similar pressure temperature conditions with values of Log R up to Experiments showed a strong effect of rock and fluid composition on reaction kinetics.

The same experimental materials and conditions but using a synthetic 0.

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